not sure of the science behind it...
I think you missed the point... Adding more hardener is not an option... You always mix acording to the directions
Oh, I gotcha now. I agree, in almost all cases involving epoxy resin, extra hardner is not an option.
Adding extra hardener
may be an option, according to the directions for the stuff I use.
I don't really understand why this would work, as the hardner in epoxy resin mates up with the resin 100% in the molecule matrix - that's why the ratio needs to be correct.
Not enough hardner results in extra un-bound resin molecules in the matrix, whereas too much hardner results in extra un-bound hardner molecules in same matrix.
For the most stable resin matrix after cure, an exact ratio needs to be followed.
Heat will speed up the curing process.